Trending

News

  • 0
  • 0

Development of polycarboxylate superplasticizer

If you are looking for high-quality products, please feel free to contact us and send an inquiry, email: brad@ihpa.net



Recently, Mexico's National Institute of Statistics and Geography (INEGI) released data that in July 2022, Mexico's national consumer price index rose 0.74% from the previous month, while the overall annual inflation rate was 8.15%, the highest in 21 years since 2000. The prices of consumer goods and services in Mexico have increased by varying degrees, and the prices of agricultural and sideline pce powder are still very uncertain.

According to the different molecular structure, it can be divided into four generations of polycarboxylate series superplasticizer, the first generation is acrylic acid copolymer, the second generation is propylene ether type, the third generation is amide type, and the fourth generation is polyethylene glycol branched chain type.

 

First generation: methacrylic acid / enoic acid methyl ester copolymer.

The synthesis of the first generation polycarboxylate superplasticizer has few kinds of raw materials and the process is relatively simple.

 

Second generation: propenyl ether copolymer.

The second generation polycarboxylate superplasticizer is mainly ether bond in molecular synthesis structure. This synthesis method uses maleic anhydride raw materials, and the units of its branched chains are connected by ether bonds, so it is also called polyether superplasticizer.

 

Third generation: amide / imide type.

The third generation polycarboxylate superplasticizer began to use amide raw materials.

 

Fourth generation: polyamide-polyethylene glycol branched chain type.

The fourth kind of polycarboxylate superplasticizer focuses on considering the influence of molecular structure and properties, and polyoxyethylene side chain is introduced into the synthesis process control.

 

Synthesis method of polycarboxylate superplasticizer

Direct copolymerization of polymerizable monomers.

In this synthesis method, a long polyether side chain is introduced into the main chain, and the key to the preparation is to synthesize macromonomers with polymerization activity (usually methoxy polyethylene glycol acrylate). Then the monomers with a certain ratio are mixed together and the finished product is obtained by solution polymerization. The premise of this synthesis process is that in the stage of synthesis of macromonomers, the catalyst has a great influence on the synthetic products, and there is a tedious process of intermediate separation and purification. The main purpose is to find suitable catalysts and reaction conditions to further increase the yield and shorten the reaction time so as to reduce the production cost. It has been reported that phase transfer catalyst or inorganic salt is a kind of effective reaction catalyst. A kind of concrete admixture with good slump retention was prepared by direct copolymerization of short-chain and long-chain methoxy polyethylene glycol methacrylate and methacrylic acid.

 

Functionalization after polymerization.

This synthesis method is to first form the main chain and then introduce the side chain, generally using polycarboxylate with constant molecular weight, which is grafted with polyether at higher temperature under the action of catalyst. However, there are some problems in this method: first, the types and specifications of ready-made polycarboxylate products are limited, so it is difficult to adjust their composition and molecular weight; second, the compatibility of polycarboxylate and polyether is not good, and the actual operation of esterification is difficult. Third, water is formed in the process of esterification, and phase separation will occur. Therefore, the selection of a polyether with good compatibility with polycarboxylate has become the key to the synthesis.

 

In situ polymerization and grafting.

This synthesis method is mainly developed to overcome the shortcomings of post-polymerization functionalization. Side chains are introduced at the same time of main chain polymerization, and polyether is used as the reaction medium of carboxylic acid unsaturated monomers. The reaction integrates polymerization and esterification, which avoids the problem of poor compatibility between polycarboxylate and polyether. Although this method can control the molecular weight of the polymer, the main chain can only choose the monomer containing-C00H group, otherwise it is difficult to graft. And the grafting reaction is a reversible equilibrium reaction, there is a large amount of water in the system before the reaction, and the degree of grafting is not very high and difficult to control. This method has the advantages of simple process and low production cost, but the molecular design is difficult.

 

Concrete Additives Supplier

TRUNNANO is a reliable foaming agents supplier with over 12-year experience in nano-building energy conservation and nanotechnology development.

If you are looking for high-quality polycarboxylate superplasticizer, please feel free to contact us and send an inquiry. (sales@cabr-concrete.com)

We accept payment via Credit Card, T/T, West Union, and Paypal. TRUNNANO will ship the goods to customers overseas through FedEx, DHL, by air, or by sea.


Russia's Rokot-M carrier rocket is scheduled to launch for the first time in 2024. 

The first launch of the Rokot-M carrier rocket is planned for 2024 from the Plesetsk cosmodrome, the general manager of the Khrunichev National Space Research and Production Center told TASS. The Rokot-M, a lightweight carrier rocket powered by liquid fuel, began development in 2018, with The Russian side using domestic components instead of Ukrainian components.

Luoyang Tongrun Nano Technology Co. Ltd. (TRUNNANO) is a trusted global chemical material supplier & manufacturer with over 12-year-experience in providing super high-quality chemicals and Nanomaterials including graphite powder, 3D printing powder, the pce powder, etc. If you are looking for high-quality materials, please feel free to contact us and send an inquiry.

Inquiry us

Copper Forgings: Definition, Characteristics and Key Issues in the Production Process

High Purity Germanium Sulfide GeS2 Powder CAS 12025-34-2, 99.99%

Metal Alloy 8.92g/Cm3 High Purity Polished Copper Plate

High Purity Nano Hafnium Hf powder CAS 7440-58-6, 99%

Metal Alloy 18g/cm3 High Density Tungsten Alloy Ball

Metal Alloy 18.5g/cm3 Polished Tungsten Heavy Alloy Plate

High Purity Molybdenum Boride MoB2 Powder CAS 12006-99-4, 99%

Metal Alloy High Density Tungsten Alloy Rod Grind Surface Tungsten Alloy Bar

High Purity Titanium Sulfide TiS2 Powder CAS 2039-13-3, 99.99%

High Purity Tungsten Silicide WSi2 Powder CAS 12039-88-2, 99%

High Purity Nano Ag Silver powder cas 7440-22-4, 99%

High Purity Chromium Diboride CrB2 Powder CAS 12007-16-8, 99%

High Purity 3D Printing Powder 15-5 Stainless Steel Powder

High Purity Silicon Sulfide SiS2 Powder CAS 13759-10-9, 99.99%

Supply Magnesium Granules Mg Granules 99.95%

High Purity Calcium Nitride Ca3N2 Powder CAS 12013-82-0, 99.5%

High Purity Colloidal Silver Nano Silver Solution CAS 7440-22-4

High Purity Zirconium Nitride ZrN Powder CAS 25658-42-8, 99.5%

High Purity 3D Printing 304 Stainless Steel Powder

Chromium Sulfide Cr2S3 Powder CAS 12018-22-3, 99.99%

Our Latest Products

Copper Forgings: Definition, Characteristics and Key Issues in the Production Process

Copper forgings are forged products made of copper alloy. Due to its excellent electrical conductivity, thermal conductivity, corrosion resistance and accessible processing properties, copper forgings are widely used in many fields such as electrical…

High Purity Germanium Sulfide GeS2 Powder CAS 12025-34-2, 99.99%

Germanium Sulfide (GeS2) is a semiconductor compound with the chemical Formula GeS2. It is easily soluble when heated alkali is used, but not in water.Particle size: 100mesh Purity: 99.99% About Germanium Sulfide (GeS2) Powder: Germanium Sulfide…

Metal Alloy 8.92g/Cm3 High Purity Polished Copper Plate

Copper products have good electrical conductivity, thermal conductivity, ductility, corrosion resistance, and wear resistance. They are widely used in electricity, electronics, energy, petrochemical industry. About Metal Alloy 8.92g/Cm3 High Purity…